Title | Recession of BN coatings in SiC/SiC composites through reaction with water vapor |
Publication Type | Journal Article |
Year of Publication | 2022 |
Authors | Collier, Virginia E., Wenbo Xu, Robert M. McMeeking, Frank W. Zok, and Matthew R. Begley |
Journal | Journal of the American Ceramic Society |
Volume | 105 |
Pagination | 498–511 |
Abstract | The mechanical response of ceramic matrix composites depends critically on the slip along the matrix–fiber interface, which is usually achieved with thin coatings on the fibers. Environmental attack of such coatings (enabled by ingress of reac- tants through matrix cracks) often leads to significant degradation, through the removal of the coating via volatilization and oxidation of exposed SiC surfaces. The extent of the volatilization region extending from the matrix crack plane (i.e., recession length) is strongly coupled to the formation of oxide, which ulti- mately fills open gaps and arrests further reactions. This paper presents models to quantify these effects over a broad range of environmental conditions, coat- ing thickness, and matrix crack opening. Analytical solutions are presented for the time to close recession gaps via oxidation, and the associated terminal reces- sion lengths obtained near free surfaces. A broad parameter study illustrates that recession behaviors are controlled by a competition between volatilization and oxidation rates. As such, the extent of recession is highly sensitive to water vapor and temperature, providing an explanation for disparate observations of reces- sion under seemingly similar conditions. The extent of recession in the interior of composites is also illustrated, using a straightforward reaction-transport model. Recession lengths decay rapidly away from the free surface, with the extent of recession penetration scaling with maximum recession at the free surface. |
URL | https://ceramics.onlinelibrary.wiley.com/doi/pdf/10.1111/jace.18052 |