| Title | A Modular Strategy for Fully Conjugated Donor-Acceptor Block Copolymers |
| Publication Type | Journal Article |
| Year of Publication | 2012 |
| Authors | S.Y. Ku, M.A. Brady, N.D. Treat, J.E. Cochran, M.J. Robb, E.J. Kramer, M.L. Chabinyc, and C.J. Hawker |
| Journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
| Volume | 134 |
| Pagination | 16040-16046 |
| Date Published | SEP 26 |
| ISSN | 0002-7863 |
| Abstract | A novel strategy for the synthesis of fully conjugated donor acceptor block copolymers, in a single reaction step employing Stille coupling polymerization of end-functional polythiophene and AA + BB monomers, is presented. The unique donor acceptor structure of these block copolymers provides a rich self-assembly behavior, with the first example of a fully conjugated donor acceptor block copolymer having two separate crystalline domains being obtained. |
| DOI | 10.1021/ja307431k |